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Beilstein J. Org. Chem. 2024, 20, 212–219, doi:10.3762/bjoc.20.21
Graphical Abstract
Scheme 1: Mumm-type rearrangement of diazo compounds.
Scheme 2: Substrate scope study of this Cu-catalyzed reaction.
Scheme 3: Control experiments.
Scheme 4: Proposed reaction mechanism.
Scheme 5: Scale-up synthesis.
Beilstein J. Org. Chem. 2016, 12, 1566–1572, doi:10.3762/bjoc.12.151
Scheme 1: Disfavored mononuclear pathway and favored dinuclear pathway in the CuAAC click reaction, according...
Figure 1: Ball-and-stick model [42,43] of a single crystal X-ray structure of hexafluorophosphate salt 1b (CCDC 1472...
Scheme 2: Synthesis of dinuclear copper complex 2.
Figure 2: Time-conversion-diagram of the CuAAC reaction of benzyl azide with either phenylacetylene or ethyl ...